23水胶REACH

Test Report

Report No.:RLSD11022110205046 Page 1 of 10

Applicant :ZHONGSHAN FUZHOU ADHESIVE-PRODUCT CO., LTD

Address :TORCH HIGH-TECH DEVELOPMENT ZONE, ZHONGSHAN CITY, GUANGDONG

PROVINCE, CHINA

Report on the submitted sample(s) said to be: Sample Name :水胶 Sample Description :White liquid Part No. Sample Received Date Testing Period

Test Requested

:01/02/03/016/036/018/013/0380/0340/014/03A/05/09/08/06 :Feb. 21, 2011

:Feb. 21, 2011 to Mar. 1, 2011

:As specified by client, to screen the 46 substances of very high concern (SVHC) under Regulation(EC) No 1907/2006 of REACH, including: Anthracene; 4,4’-Diaminodiphenylmethane; Dibutyl phthalate;

Cobalt dichloride; Diarsenic pentaoxide; Diarsenic trioxide; Sodium dichromate; Musk-xylene; Bis(2-ethyl(hexyl)phthalate)(DEHP);

Hexabromocyclododecane(HBCDD); Short Chain Chlorinated Paraffins; Bis(tributyltin)oxide; Lead hydrogen arsenate; Benzyl butyl phthalate; Triethyl Arsenate; Anthracene oil; four types of Anthracene oil fractions; Coal tar pitch, high temperature; Acrylamide; Aluminiosilicate, Refractory Ceramic Fibres; Zirconia Aluminosilicate, Refractory Ceramic Fibres; 2,4-Dinitrotoluene; Diisobutyl phthalate (DIBP); Lead chromate; Lead

chromate molybdate sulphate red (C.I. Pigment Red 104); Lead sulfochromate yellow(C.I. Pigment Yellow 34); Tris(2-chloroethyl)phosphate (TCEP) ; Trichloroethylene; Boric acid; Disodium tetraborate, anhydrous; Tetraboron disodium heptaoxide, hydrate; Sodium chromate; Potassium chromate; Ammonium dichromate; Potassium dichromate; Cobalt(Ⅱ) sulphate, Cobalt(Ⅱ) dinitrate, Cobalt(Ⅱ) carbonate, Cobalt(Ⅱ) diacetate,

2-Methoxyethanol, 2-Ethoxyethanol, Chromium trioxide, Acids generated from chromium trioxide and their oligomers: Chromic acid, Dichromic acid, Oligomers of chromic acid and dichromic acid in the submitted sample.

Test Method/ Test Result(s) :Please refer to the following page(s).

:According to the analytical results, concentrations of 46 SVHC substances Summary

are less than 0.1% in the submitted sample.

Tested by Inspected by

Approved by Date Mar. 1, 2011 Technical Manager No.03186856

Test Report

Substance Name(s)

Anthracene 4,4’-

Test Method and Equipments GS ZEK 01.2-08, GC-MS Refer to US EPA 3550C:2007& US EPA 8270D:2007, GC-MS Refer to EN 14372-2004, GC-MS Refer to US EPA 3052:1996/ BS EN14582:2007, ICP-OES/IC Refer to US EPA 3052:1996, ICP-OES Refer to US EPA 3052:1996, ICP-OES

Refer to US EPA 3052:1996/

Sodium dichromate*

Musk xylene

US EPA3060A:1996, ICP-OES/UV-Vis

Refer to US EPA 3540C:1996, GC-MS Refer to EN 14372-2004, GC-MS Refer to US EPA 3540C:1996, GC-MS Refer to US EPA 3540C:1996, GC-MS

Refer to US EPA 3052:1996/ DIN 38407:2003, ICP-OES/GC-MS Refer to US EPA 3052:1996, ICP-OES Refer to EN 14372-2004, GC-MS Refer to US EPA 3052:1996, ICP-OES

Substance Classification

PBT Carcinogen, cat. 2 Toxic for reproduction, cat.2

Carcinogen, cat.2 Carcinogen, cat.1 Carcinogen, cat.1 Carcinogen, cat.2; Mutagen, cat.2; Toxic for reproduction, cat.2

vPvB

Toxic for reproduction, cat.2

PBT PBT; vPvB PBT Carcinogen, cat.1; Toxic for reproduction, cat.1 Toxic for reproduction, cat.2

Carcinogen, cat.1

0.005% 0.005% 0.005% 0.01% 0.005% 0.01% 0.005% 0.01% 0.01% Report Limit 0.005% 0.005% 0.005% 0.01% 0.01% 0.01%

Report No.:RLSD11022110205046 Page 2 of 10 Test Method:

Diaminodiphenylmethane Dibutyl phthalate(DBP) Cobalt dichloride* Diarsenic pentaoxide* Diarsenic trioxide*

Bis(2-ethyl(hexyl)phthalate)

(DEHP)

Hexabromocyclododecane

(HBCDD) Short Chain Chlorinated Paraffins(SCCPs) Bis(tributyltin)oxide (TBTO)* Lead hydrogen arsenate* Benzyl butyl phthalate(BBP)

Triethyl arsenate*

Test Report

Substance Name(s)

①

Report No.:RLSD11022110205046 Page 3 of 10 Test Method:

Test Method and Equipments In-house method, GC-MS In-house method, GC-MS In-house method, GC-MS In-house method, GC-MS In-house method, GC-MS In-house method, GC-MS In-house method, ICP-OES/SEM-EDS In-house method, ICP-OES/SEM-EDS

In-house method, GC-MS In-house method, HPLC Refer to EN 14372-2004, GC-MS Refer to US EPA 3052:1996/

②

Substance Classification

PBT PBT PBT PBT PBT

PBT; Carcinogen, cat.2 Carcinogen, cat.2 Carcinogen, cat.2 Carcinogen, cat.2 Carcinogen, cat.2; Mutagen, cat.2 Toxic for reproduction, cat.2

Carcinogen, cat.2; Toxic for reproduction, cat.1

Carcinogen, cat.2; Toxic for reproduction, cat.1

Carcinogen, cat.2; Toxic for reproduction, cat.1 Toxic for reproduction, cat.2

Report Limit 0.05% 0.05% 0.05% 0.05% 0.05% 0.05% 0.05% 0.05% 0.01% 0.01% 0.005% 0.05%

Anthracene oil

①

Anthracene oil, anthracene paste,

distn. Lights**** Anthracene oil, anthracene paste,

anthracene fraction Anthracene oil, anthracene-low

①

①

①

Anthracene oil, anthracene paste Coal tar pitch, high temperature

②

①

Aluminiosilicate, Refractory

Ceramic Fibres

②

Zirconia Aluminosilicate, 2,4-Dinitrotoluene Acrylamide

Refractory Ceramic Fibres

Diisobutyl phthalate (DIBP)

Lead chromate

US EPA 3060A:1996, ICP-OES/UV-Vis Refer to US EPA 3052:1996/ US EPA 3060A:1996, ICP-OES/UV-Vis Refer to US EPA 3052:1996/ US EPA 3060A:1996, ICP-OES/UV-Vis In-house method, GC-MS

②

Lead chromate molybdate sulphate red

(C.I. Pigment Red 104)***

②

0.05%

Lead sulfochromate yellow

(C.I. Pigment Yellow 34)*** Tris(2-chloroethyl)phosphate (TCEP)

0.05% 0.01%

Test Report

Substance Name(s) Trichloroethylene

③

Report No.:RLSD11022110205046 Page 4 of 10 Test Method:

Test Method and Equipments Refer to US EPA 5021:1996,

Headspace-GC/MS Refer to US EPA 3052:1996,

ICP-OES

Refer to US EPA 3052:1996,

ICP-OES

Refer to US EPA 3052:1996,

ICP-OES

Refer to US EPA 3052:1996/

④

Substance Classification Carcinogen, cat.2

Toxic for reproduction,cat2

Toxic for reproduction,cat2

Toxic for reproduction,cat2 Carcinogen, cat.2; Mutagenic cat2; Toxic for reproduction,cat2 Carcinogen, cat.2; Mutagenic cat2 Carcinogen, cat.2; Mutagenic cat2; Toxic for reproduction,cat2 Carcinogen, cat.2; Mutagenic cat2; Toxic for reproduction,cat2

Report Limit 0.005% 0.01% 0.01% 0.01%

Boric acid

③

Disodium tetraborate, anhydrous*****

③

Tetraboron disodium heptaoxide,

hydrate*****

Sodium chromate US EPA 3060A:1996, ICP-OES/UV-Vis Refer to US EPA 3052:1996/

0.01%

④

Potassium chromate US EPA 3060A:1996, ICP-OES/UV-Vis Refer to US EPA 3052:1996/

0.01%

④

Ammonium dichromate US EPA 3060A:1996, ICP-OES/UV-Vis Refer to US EPA 3052:1996/

0.01%

④

Potassium dichromate US EPA 3060A:1996, ICP-OES/UV-Vis

0.01%

Test Report

Substance Name(s)

⑤

Report No.:RLSD11022110205046 Page 5 of 10 Test Method:

Test Method and Equipments Refer to US EPA 3052:1996 & in-house method/ICP-OES & IC Refer to US EPA 3052:1996 & in-house method/ICP-OES & IC Refer to US EPA 3052:1996 & in-house method/ICP-OES & IC Refer to US EPA 3052:1996 & in-house method/ICP-OES & IC Refer to US EPA 3550C:2007

/GC-MS

Refer to US EPA 3550C:2007

/GC-MS

Refer to US EPA3052:1996 &

⑤

Substance Classification Toxic for reproduction,cat.2

Carcinogen, cat 2 Toxic for reproduction,cat.2

Carcinogen, cat 2 Toxic for reproduction,cat.2

Carcinogen, cat 2 Toxic for reproduction,cat2

Carcinogen, cat 2 Toxic for reproduction, cat 2 Toxic for reproduction, cat 2

Carcinogen, cat 1; Mutagenic cat 2

Report Limit 0.01% 0.01% 0.01% 0.01% 0.005% 0.005%

Cobalt(Ⅱ) sulphate Cobalt(Ⅱ) dinitrate

⑤

⑤

Cobalt(Ⅱ) carbonate Cobalt(Ⅱ) diacetate 2-Methoxyethanol 2-Ethoxyethanol

⑤

Chromium trioxide US EPA3060A:1996/ ICP-OES & UV-Vis

0.01%

⑤

Acids generated from chromium trioxide and their oligomers: Chromic acid, Dichromic acid, Oligomers of chromic acid and

dichromic acid

Refer to US EPA3052:1996 &

US EPA3060A:1996/ ICP-OES & UV-Vis

Carcinogen, cat 2

0.01%

Test Report

Substance Name(s)

Anthracene

4,4’- Diaminodiphenylmethane Dibutyl phthalate(DBP) Cobalt dichloride* Diarsenic pentaoxide* Diarsenic trioxide* Sodium dichromate*

Musk xylene

Bis(2-ethyl(hexyl)phthalate)(DEHP) Hexabromocyclododecane (HBCDD) Short Chain Chlorinated Paraffins(SCCPs)

Bis(tributyltin)oxide (TBTO)* Lead hydrogen arsenate* Benzyl butyl phthalate(BBP)

Triethyl arsenate*

①

①

Report No.:RLSD11022110205046 Page 6 of 10 Test Result(s):

CAS No. 120-12-7 101-77-9 84-74-2 76-79-9 1303-28-2 1327-53-3 77-12-0/ 10588-01-9 81-15-2 117-81-7 25637-99-4/ 3194-55-6 85535-84-8 56-35-9 7784-40-9 85-68-7 15606-95-8 900-80-5 91995-17-4 91995-15-2 900-82-7 900-81-6 65996-93-2 79-06-1 - - 121-14-2 84-69-5 7758-97-6 12656-85-8 1344-37-2 115-96-8

EC No. 204-371-1 202-974-4 201-557-4 231-5-4 215-116-9 215-481-4 234-190-3 201-329-4 204-211-0 247-148-4/ 221-695-9 287-476-5 200-268-0 232-0-2 201-622-7 427-700-2 292-602-7 295-278-5 295-275-9 292-604-8 292-603-2 266-028-2 201-173-7 650-017-00-8** 650-017-00-8** 204-450-0 201-553-2 231-846-0 235-759-9 215-693-7 204-118-5

Concentration(%)

N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D.

Anthracene oil

Anthracene oil,anthracene paste,

distn. Lights ****

①

Anthracene oil, anthracene paste,

anthracene fraction Anthracene oil, anthracene-low Anthracene oil, anthracene paste Coal tar pitch, high temperature

Acrylamide

①①

①

②

Aluminiosilicate, Refractory Ceramic Fibres

②

Zirconia Aluminosilicate, Refractory Ceramic Fibres

2,4-Dinitrotoluene

Diisobutyl phthalate (DIBP)

②

②

Lead chromate

Lead chromate molybdate sulphate red

(C.I. Pigment Red 104)***

Lead sulfochromate yellow (C.I. Pigment Yellow 34)***

②

Tris(2-chloroethyl)phosphate (TCEP)

Test Report

Substance Name(s) Trichloroethylene

③

Report No.:RLSD11022110205046 Page 7 of 10 Test Result(s) :

CAS No. 79-01-6 10043-35-3 11113-50-1 1330-43-4 12179-04-3 1303-96-4 12267-73-1 7775-11-3 77-00-6 77-09-5 7778-50-9 10124-43-3 10141-05-6 513-79-1 71-48-7 109-86-4 110-80-5 1333-82-0 7738-94-5 13530-68-2

EC No. 201-167-4 233-139-2 234-343-4 215-540-4

Concentration(%)

N.D. N.D.

Boric acid

③

Disodium tetraborate, anhydrous*****

③

N.D.

Tetraboron disodium heptaoxide,

hydrate*****

④④④

235-541-3 231-8-5 232-140-5 232-143-1 231-906-6 233-334-2 233-402-1 208-169-4 200-755-8 203-713-7 203-804-1 215-607-8 231-801-5 236-881-5

N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D. N.D.

Sodium chromate

Potassium chromate

Ammonium dichromate Potassium dichromate Cobalt(Ⅱ) sulphate Cobalt(Ⅱ) dinitrate

⑤⑤⑤

④

Cobalt(Ⅱ) carbonate Cobalt(Ⅱ) diacetate 2-Methoxyethanol 2-Ethoxyethanol

⑤

⑤

⑤

Chromium trioxide

Acids generated from chromium trioxide and their oligomers: Chromic acid, Dichromic acid, Oligomers of chromic acid

and dichromic acid

N.D.

Test Report

Report No.:RLSD11022110205046 Page 8 of 10 Note:

-N.D. = Not Detected (-PBT= Persistent,Bioaccumulative,Toxic; vPvB=very Persistent very Bioaccumulative

-*:Concentration value of Cobalt dichloride by the conversion from the test results of Cobalt and Chlorine. Concentration value of Diarsenic pentaoxide, Diarsenic trioxide, Sodium dichromate, Lead hydrogen arsenate, Triethyl arsenate by the conversion from the test results of corresponding heavy metal.

Concentration value of Bis(tributyltin)oxide by the conversion from the test results of Tributyl Tins. -**:All refractory ceramic fibres are covered by index number 650-017-00-8 in Annex VI of the Regulation on Classification, Labeling and Packaging of chemical substances and mixtures, the so called CLP Regulation (Regulation (EC) No 1272/2008). -***: C.I.: Colour Index

-****:Light fractions from distillation

-*****:Concentration value of Boric acid Disodium tetraborate, anhydrous and Tetraboron disodium

heptaoxide, hydrate is evaluated by Disodium tetraborate, with no consider of the hydrate. ①

-:In view of the substances are established as UVCB substances (substances of unknown or variable composition, complex reaction products or biological materials) consisting of different and variable constituents, the test results are calculated based on the main constituents of the representative compounds for substances. ②

-:In view of the substance contain variable substances, the test results are calculated based on main constituents of the representative compounds for the substances, and the test results of the representative compounds are calculated based on the result of specified heavy metal elements. ③

-: Concentration value of Boric acid;Disodium tetraborate, anhydrous;Tetraboron disodium heptaoxide, hydrate are calculated by the conversion from the test results of corresponding

metals and confirmed by appropriate solvent extraction, meanwhile the book of materials is suggested to be checked for further confirmation. ④

-: Concentration value of Sodium chromate;Potassium chromate;Ammonium dichromate;

Potassium dichromate are calculated by the conversion from the test results of corresponding metals. ⑤

-:Concentration values of Cobalt(Ⅱ) sulphate, Cobalt(Ⅱ) dinitrate, Cobalt(Ⅱ) carbonate, Cobalt(Ⅱ) diacetate, Chromium trioxide ,Chromic acid, Dichromic acid, and Oligomers of chromic acid and dichromic acid are calculated by the conversion from the test results of corresponding heavy metals and confirmed by appropriate solvent extraction, meanwhile the book of materials is suggested to be checked for further confirmation.

Remark: The report limit is evaluated based on the representative substances.

Test Report

Report No.:RLSD11022110205046 Page 9 of 10 Appendix:

1. According to the Article 33 of the Regulation (EC) No 1907/2006 (REACH)-Duty to communicate information on substances in articles.

—Any supplier of an article containing a substance meeting the criteria in Article 57 and identified in accordance with Article 59(1) in a concentration above 0.1 % weight by weight (w/w) shall provide the recipient of the article with sufficient information, available to the supplier, to allow safe use of the article including, as a minimum, the name of that substance.

—On request by a consumer any supplier of an article containing a substance meeting the criteria in Article 57 and identified in accordance with Article 59(1) in a concentration above 0.1 % weight by weight (w/w) shall provide the consumer with sufficient information, available to the supplier, to allow safe use of the article including, as a minimum, the name of that substance. The relevant information shall be provided, free of charge, within 45 days of receipt of the request.

2. According to the Article 33 of the Regulation (EC) No 1907/2006 (REACH)- Notification of the Substance in Article.

—If a substance meets the criteria in Article 57 and is identified in accordance with Article 59(1), EU and EEA producers or importers of articles have to notify ECHA when their article contains a substance on the Candidate List. This obligation applies if the substance is present above 0.1% (w/w) and its quantities in the produced/imported articles are above 1 tonne in total per year.

3. According to the other articles of the Regulation (EC) No 1907/2006 (REACH), The relevant obligation for the substance on its own or in preparation. —OBLIGATIONS: SUBSTANCES

From 28 October 2008, EU & EEA suppliers of a substance have to provide a safety data sheet to their customers when the substance is on the Candidate List. —OBLIGATIONS: PREPARATIONS

From 28 October 2008, EU and EEA suppliers of a preparation not classified as dangerous according to Directive 1999/45/EC have to provide the recipients, at their request, with a safety data sheet if the preparation contains at least one substance on the Candidate List and its individual concentration is at least 0.1% (w/w) for non gaseous preparations and at least 0.2% by volume for gaseous preparations.

Test Report

Photo(s) of the sample(s)

Report No.:RLSD11022110205046 Page 10 of 10

*** End of report ***

This report is considered invalidated without the Special Seal for Inspection of the CTI, This report shall not be altered, increased or deleted. The results shown in this test report refer only to the sample(s) tested. Without written approval of CTI, this test report shall not be copied except in full and published as advertisement.

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