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Process for the preparation of diphenylamine or nu

来源:九壹网
专利内容由知识产权出版社提供

专利名称:Process for the preparation of

diphenylamine or nucleus- substitutedderivative thereof

发明人:Teruyuki Nagata,Chiyuki Kusuda,Masaru

Wada

申请号:US08/458294申请日:19950602公开号:US05545752A公开日:19960813

摘要:A processes for the preparation of diphenylamine or a nucleus- substitutedderivative thereof, which comprise, upon feeding into a reaction system a phenol

compound and reacting in the reaction system a cyclohexanone compound with an anilinecompound in the presence of a hydrogen transfer catalyst and a catalytic amount of thecyclohexanone compound corresponding to the phenol compound while using thephenol compound as a hydrogen acceptor and forming the cyclohexanone compound inthe reaction system, (1) conducting reaction while adding dropwise the aniline compoundand (2) employing a hydroxide, carbonate or bicarbonate of an alkali metal and/oralkaline earth metal when the hydrogen transfer catalyst is one of noble metals of GroupVIII of the periodic table, respectively.

申请人:MITSUI TOATSU CHEMICALS, INC.

代理机构:Burns, Doane, Swecker & Mathis

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